Towards better batteries and fuel cells with dispersibility estimation for carbon electrode slurries

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Carbon slurries, which consist of a suspension of carbon particles in a solvent, are used to mass-produce battery electrodes. However, there are no adequate methods to evaluate whether the particles are uniformly dispersed in the slurry during the manufacturing process. In a recent study, researchers used an innovative approach, combining viscosity and electrochemical impedance measurements, to accurately assess the dispersibility of slurries, opening doors to enhanced electric vehicles and fuel cell batteries.

Lithium-ion batteries are the powerhouse of modern-day electronics, and fuel cells are a promising candidate for sustainable energy devices. An important factor affecting the performance of both lithium-ion batteries and fuel cells is the dispersibility of carbon slurries, suspensions made of conductive carbon particles dispersed in a solvent. They can be easily coated on a metal collector to mass-produce electrodes.

Against this backdrop, a research team led by Associate Professor Isao Shitanda from Tokyo University of Science in Japan developed a novel technique to estimate the dispersibility of carbon slurries. Their latest study, published online inon 1 August 2023, is co-authored by Dr. Yoshifumi Yamagata from Anton Paar Japan K. K. and Dr. Shingo Niinobe from Shin-Etsu Chemical Co., Ltd.

Additionally, the team developed an equivalent circuit model consisting of three types of contact resistances and capacitances: those between acetylene black particles, those of particle bulk, and those arising from the design of the measurement setup. The bulk resistance of acetylene black showed no dependence on shear rate but decreased with increase in the methylcellulose concentration.

Preparing slurries with higher dispersibility could also lead to improved lithium-ion battery performance and enhanced functional materials. These would be significant contributions toward building a sustainable carbon-neutral society by fostering applications in solar panels, fuel cells, and electric vehicles.

 

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